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We know that,
Then,
= 110.87 g mol−1
= 196.15 g mol−1
Now, we have the molar masses of AB2 and AB4 as 110.87 g mol−1 and 196.15 g mol−1 respectively.
Let the atomic masses of A and B be x and y respectively.
Now, we can write:
Subtracting equation (i) from (ii), we have
2y = 85.28
⇒ y = 42.64
Putting the value of ‘y’ in equation (1), we have
x + 2 × 42.64 = 110.87
⇒ x = 25.59
Hence, the atomic masses of A and B are 25.59 u and 42.64 u respectively.
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